A risk-based decision making approach to determine fireproofing requirements against jet fires

API Publication 2218 is one of the most referred practices for fireproofing of onshore structural supports. Despite the extensive citation, it solely considers the effects of pool fire and rarely addresses jet fire outcomes. This absence of an explicit approach is common among all the other major references. Therefore, the basic objective of this paper is to introduce a new approach for determination of the necessity for fireproofing of structural supports against jet fires. For this purpose, the flame geometry and duration of jet fires are simulated for different leak sizes in identified fire potential sources. Then, following a worst-case analysis, those structures that may be impinged by long enough flames are screened out and then characterized by maximum impingement duration for fireproofing purpose. Moreover, each structure is assigned by a failure rate to estimate the degree of vulnerability through a detailed risk assessment. In this regard a new explanatory term called Structure Failure Rate (SFR) is introduced. This approach also enables researchers to quantify the effect of other protective systems (fire and gas detection, emergency shut-down, depressurization and firewalls) on the level of required fireproofing.     

Evolution of solid waste management in Malaysia: impacts and implications of the solid waste bill, 2007

Solid waste generation and its implications for people and the environment are global issues. The complexity of the waste composition and the ever-increasing percapita waste generation is a challenge for waste managers, particularly in developing countries. Thus, the need to have a clear policy on waste management and legislation to realize that policy is imperative. Malaysia is developing rapidly and problems such as the waste generation associated with development and industrialization are evident. The Solid Waste and Public Cleansing Management Bill, which was approved in August 2007 after a 10-year delay, is envisaged to have serious consequences in waste management practices and implementation in Malaysia. This article explores the main features of this all-encompassing bill and its impacts on the waste management scenario in Malaysia. In addition, a comparative evaluation is also discussed to explore the policies/legislation of selected countries vis-àvis the Malaysian bill.     

Implementing single- and multi-year sensitivity analyses to propose several feasible solutions for meeting the electricity demand in large-scale tourism sectors applying renewable systems

Environment, Development and Sustainability - The tourism sectors consume a high amount of electrical power, which in most cases is supplied by the electrical grid and diesel generator. As a...     

Movement towards a low carbon emitted environment: a test of some factors in Malaysia

There exists a high global concern in different nations on environmental sustainability especially at the focal stage of increased economic growth and development process due to high level of environmental degradation and pollution. The major aim of this study was to empirically examine how to minimise carbon emissions (CO₂) in Malaysia which are mainly caused by energy production, fossil fuel consumption, population density and economic growth. The study adopted the method of autoregressive distributed lag bound testing approach to analyse the data for the period 1971–2011. The study found that economic growth in Malaysia has a direct relationship with CO₂ emissions in both the short run and the long run. Similarly, there is a positive relationship between fossil fuel consumption and CO₂ emissions over the same period. Population density was found to have positive impacts on CO₂ emissions. Contrarily, the relationship between the activities of energy production and pollution is negative in the long run. The study recommends that a targeted GDP growth rate should be set with the consideration to avoid more environmental pollution. In addition, the positive impact of fossil fuel consumption on the environmental pollution implies that there is a need to make and implement policies that will encourage the use of public transportation system more than private transportations. That is, the unnecessary use of private vehicles should be discouraged in order to reduce the extent of fossil fuel consumption.     

Preparation and characterization of polycaprolactone nanocapsules containing pretilachlor as a herbicide nanocarrier

Polycaprolactone nanocapsules (PCL) containing pretilachlor were prepared, and Fourier transform infrared spectroscopy, atomic force microscopy, and transmission electron microscopy were used for their structural and morphological investigations. The results revealed that the nanocapsules had irregular shape and their particles size was in the range of 70–200 nm. The encapsulation efficiency of pretilachlor was measured as 99.5 ± 1.3% using high-performance liquid chromatography analysis. The physicochemical stability studies over 60 days showed that the nanocapsules were stable in the suspension without any aggregation. The herbicide activity was examined in a pre-emergence manner using barnyard grass as a target plant and rice as a non-target plant. The nanoformulation had no negative effect on rice plant. However, its effect on barnyard grass was significant. The cytotoxicity analysis indicated that the nanocapsulated herbicide is less toxic rather than the commercial formulation. Therefore, encapsulation of pretilachlor in PCL nanocapsules can be used effectively to construct environmentally friendly PCL-herbicide systems in agriculture.

     

North–South Investment Flows and Optimal Environmental Policies

In the context of a simple North–South model that focuses on the international movement of capital, we show how neglect of pollution-generating effects of foreign investment may lead to distorted and misleading policy recommendations. Such a neglect has recently received emphasis in the empirical literature on East Asian economies, as in Bello and Rosenfeld (1990, “Dragons in Distress: Asia's Miracle Economics in Crisis,” Food First, San Francisco), and was shown to overlook resulting tendencies in these economies toward specialization, away from agriculture and toward manufacturing. Our simple model formalizes this observation and allows us to show that even for an unspecialized capital-poor, resource-rich South, such pollution-generating effects provide incentives for the North to encourage, rather than to discourage, foreign investment abroad and strengthen Southern incentives to restrict foreign investment more sharply than is conventionally assumed. In a nutshell, it brings out the implications of Northern capital “creating its own demand” as a consequence of its adverse impact on the Southern resource base. Despite its simplicity, the model thus sheds light on three interrelated aspects of international trading relations: production asymmetry, incomplete markets, and monopolistic advantage.     

Ultra-sensitive quantification of copper in food and water samples by electrochemical adsorptive stripping voltammetry

A new electrochemical adsorptive stripping voltammetry method was developed for the determination of trace amounts of copper in food and water samples. The study of electrochemical behavior of Cu ion indicated that Cu(II) and Schiff base formed a complex in H₃BO₄–NaOH buffer solution (pH?=?7.25). An accumulation potential of ?100 mV (vs Ag/AgCl) was applied while the solution was stirred for 60 s. The response curve was recorded by scanning the potential, and the peak current of ?0.31 V (vs Ag/AgCl) was recorded. The peak current and concentration of copper accorded with linear relationship in the range of 0.04–120 ng mL^?1. The relative standard deviation (for 12 ng mL^?1 of copper) was 1.73 %, and the detection limit was 0.007 ng mL^?1. The possible interference of some common ions was studied. The proposed method was applied to the determination of copper in water, rice, wheat, tea, milk, and tomato with satisfactory results.     

Application of a multi-plant QRA: A case study investigating the risk impact of the construction of a new plant on an existing chemical plant's risk levels

The construction of chemical clusters whereby a variety of chemical plants are located next to each other provides great economic benefits. However, in such clusters, due to the mere scale on which hazardous materials are processed, stored and handled, the potential of various accidents is much higher than in single companies. Furthermore, the close proximity of process installations and storage tanks in such areas gives rise to the risk of domino effects. Therefore, land use planning and layout design has always been a challenge within such clusters.In this paper, a Quantitative Risk Assessment (QRA) is carried out and used as a decision making tool to evaluate the acceptability of constructing a new chemical plant adjacent to an existing one. For this purpose, standard parameters such as individual risk and societal risk were quantified, before and after the new plant would come into operation. Given the experience of past accidents in the process industries, the likelihood of domino accidents in the two neighboring plants has also been analyzed.     

土地利用变化下的生态系统服务敏感性研究——以克里雅绿洲为例

通过剖析传统的敏感性分析法,提出交叉敏感性概念,评价生态服务价值对土地利用类型转换的响应性。以克里雅绿洲为研究区域,以1991、2002 和2011 年三期遥感影像数据为基本信息源,运用交叉敏感性分析,计算生态系统服务价值对土地利用类型转换的敏感性,确定生态系统日趋敏感的土地利用变化过程,为土地管理对策提供参考依据。研究结果表明:20 a来,克里雅绿洲生态服务价值较敏感的土地利用转换类型相对稳定,主要集中在湿地和水体向荒漠和低覆盖度草地的转换;与1991 和2011 年相比,2002 年的交叉敏感性系数普遍上升,这主要是因为湿地、水体面积的减少加剧了研究区的生态脆弱性,从而表现出更大的敏感性;湿地和水体向耕地转换的交叉敏感性一直处于上升趋势,并不断接近于-1,表明生态服务价值对高强度的人为活动变得越来越敏感,从而警示地方管理部门采取必要措施制止此种转换的持续。     

Sequential UV-biological degradation of chlorophenols

The sequential UV-biological degradation of a mixture of 4-chlorophenol (CP), 2,4-dichlorophenol (DCP), 2,4,6-trichlorophenol (TCP), and pentachlorophenol (PCP) was first tested with each pollutant supplied at an initial concentration of 50 mg l(-1). Under these conditions, the chlorophenols were photodegraded in the following order of removal rate: PCP>TCP>DCP>CP with only CP and DCP remaining after 40 h of irradiation. The remaining CP (41 mg l(-1)) and DCP (13 mg l(-1)) were then completely removed by biological treatment with an activated sludge mixed culture. Biodegradation did not occur in similar tests conducted with a non-irradiated mixture due to the high microbial toxicity of the solution. UV treatment lead to a significant reduction of the phytotoxicity to Lipedium sativum but no further reduction of phytotoxicity was observed after biological treatment. Evidence was found that the pollutants were partially photodegraded into toxic and non-biodegradable products. When the pollutants were tested individually (initial concentration of 50 mg l(-1)), PCP, TCP, DCP, 4-CP were photodegraded according to first order kinetic model (r2>99) with half-lives of 2.2, 3.3, 5.7, and 54 h, respectively. The photoproducts were subsequently biodegraded. This study illustrates the potential of UV as pre-treatment for biological treatment in order to remove toxicity and enhance the biodegradability of organic contaminants. However, it also shows that UV treatment must be carefully optimized to avoid the formation of toxic and/or recalcitrant photoproducts and results from studies conducted on single contaminants cannot be extrapolated to mixtures.